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FeCl_3催化的溴代芳烃与取代硫酚的偶联:合成二芳基硫醚 被引量：1

Synthesis of diaryl thioethers from bromoarenes and substituted thiophenols catalyzed by FeCl_3
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摘要 以FeCl3为催化剂,L-脯氨酸为配体,以K2CO3为碱,在氮气的保护下在乙二醇二甲醚中回流,有效促进了溴代芳烃和取代硫酚的偶联反应生成相应的硫醚,产物的收率较高. Diaryl thioethers were effectively synthesized from coupling reaction of bromoarenes and substituted thiophenols with K2CO3 catalyzed by FeCl3 in the presence of L-proline at reflux in dimethoxyethane under nitrogen atmosphere.
作者 李龙彪 吴剑娇 陈仁尔 周其忠 徐土根 蒋华江
机构地区 台州学院化学系 杭州师范大学材料与化学化工学院
出处 《浙江大学学报（理学版）》 CAS CSCD 2012年第3期313-316,共4页 Journal of Zhejiang University（Science Edition）
基金 国家自然科学基金资助项目(21172166) 浙江省自然科学基金资助项目(Y4100783) 浙江省教育厅科研计划资助项目(20061048)
关键词 FECL3 L-脯氨酸 溴代芳烃 硫酚 偶联 FeCl3 L-proline bromoarenes thiophenol coupling
分类号 O625.72 [理学—有机化学]
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浙江大学学报（理学版）
2012年 第3期

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