期刊文献+

Electro-deposition tangsten coating on low activation steel substrates from Na_2WO_4-ZnO-WO_3 melt salt

Electro-deposition tangsten coating on low activation steel substrates from Na_2WO_4-ZnO-WO_3 melt salt
下载PDF
导出
摘要 Tungsten coating is considered as a promising alternative material for plasma facing materials(PFC) in future fusion devices.The electro-deposition of tungsten in Na_2WO_4-ZnO-WO_3 melt at 1173 K on low activation steel substrates was studied in this work.Adherent and smooth tungsten films were deposited under various pulsed current conditions.The crystal structure and microstructure of tungsten deposits were characterized by XRD,SEM and EDX techniques.The results show that pulsed current density and duty cycle have a significant influence on tungsten nucleation and electro-crystallization phenomena.Uniform and smooth tungsten coating with high purity and high adherence is obtained on low active steel substrates as cathodic current density ranges from 35 to 25 mA·cm_(-2).
出处 《Rare Metals》 SCIE EI CAS CSCD 2012年第4期350-354,共5页 稀有金属(英文版)
基金 supported by the International Thermonuclear Experimental Reactor (ITER) Project of China (No. 2010GB109000) the National Natural Science Foundation of China (No. 50972008)
关键词 TUNGSTEN ELECTRO-DEPOSITION low activation steel pulse current MELT tungsten electro-deposition low activation steel pulse current melt
  • 相关文献

参考文献6

二级参考文献45

  • 1文振环,李国勋.KF-B_2O_3-K_2WO_4熔体中电镀钨的研究─—周期反向电流(PRC)[J].稀有金属,1994,18(3):161-166. 被引量:3
  • 2文振环,李国勋.钨在铂电极上成核动力学研究[J].电镀与精饰,1995,17(4):4-6. 被引量:2
  • 3史乃立 蔡幼庆.金属枝晶生长方向的研究[J].应用科学学报,1984,2(1):49-55.
  • 4[1]Swnderoff S, Mellors G W. Coherent coating of refractory metals [J]. Science, 1976, 153 (3743): 1575.
  • 5[2]White S H, Twardich V M. The chemistry and electrochemistry associated with the electroplating of group VIA transition [J]. J.Appl. Electrochem., 1987, 17: 225.
  • 6[3]Mamantov G. Electrochemistry and related studios in molten halides [A]. In Proc. 1st. Inter. Symp.on Molten Salts [C]. The Electrochem Soc., 1976. 234.
  • 7[4]Akatagiri. Electrodeposition of tungsten in ZnBr2-NaBr and ZnCl2-NaCl metls [J]. J. Electrochem. Soc., 1991, 138 (3):767.
  • 8[5]McCawley F X, Kenahan C B. Electrodeposition of tungsten and molybdenum from fused salt baths [J]. J.Metals, 1964, 17:92.
  • 9[6]Malyshev V V. Electrochemical deposition and the properties of W coatings deposited from tungstate melts [J]. Metal Abs.,1977, 35: 1230.
  • 10[10]Koyama K, Hashimoto Y. Liquids surfaces of the KF-B2O3-Li2WO4, KF-B2O3-Na2WO4 and KF-B2O3-K2WO4 systems [J].J.Metals, 1988, 141: 55.

共引文献41

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部