2(3)-(N,N-二乙酸氨基)-9(10),16(17),23(24)-(N,N-二乙基氨基)酞菁锌的合成、表征和光谱性质

2(3)-(N,N-ethanedioicacid-amino)-9(10),16(17),23(24)-(N,N-diethylamine-amino) Phthalocypanine zinc

以4-硝基邻苯二甲腈、亚氨基二乙酸、二乙胺等化合物为原料合成了2(3)-(N,N-二乙酸氨基)-9(10),16(17),23(24)-(N,N-二乙基氨基)酞菁锌,通过IR、核磁、元素分析、UV-Vis和荧光光谱等对其结构进行了表征,并研究合成产物的光物理性质。结果表明所合成的化合物具有好的溶解性,在DMF中不发生集聚现象,紫外可见光谱发生明显红移。

The synthesis of 2(3)-(N,N-ethanedioicacid-amino)-9(10),16(17),23(24) -(N,N-diethylamine-amino) Phthalocypanine zinc from 4-nitro-phthalonitrile was investigated. The complexe was characterized by IR, UV-Vis, Fluorescence and dissolvability. The results show that substituent on phthalocyanines result in the increase of solubility and hindering the dimerization as well as the red shift for UV-Vis of synthesized compound.