石墨炉原子吸收法测定空气中铋

Determination of bismuth in the air by Graphite Furnace Atomic Absorption Spectrometry

建立了硝酸-双氧水体系消解、石墨炉原子吸收法测定空气中铋的方法。采用抗坏血酸和磷酸二氢铵作混合基体改进剂,热解涂层石墨管,塞曼扣背景。此方法对测定环境空气中铋的灵敏度、准确度都有很大的提高,方法的最低检出浓度为1.00μg/L,当采样体积为150L,铋最低检出质量浓度为0.0007mg/m3。

To establish a method for determination of bismuth nitrate in air - hydrogen peroxide system, di-gestion and graphite furnace atomic absorption spectrometry. The ascorbic acid and two hydrogen ammonium phosphate as a mixed matrix modifier, pyrolytic coated graphite tube, Zeeman background correction. The sen-sitivity of this method, determination of bismuth in ambient air the accuracy is greatly improved, the minimum detection limit was 1 μg/L, when the sampling volume was 150L, the minimum detectable concentration of 0. 0007mg/m3 bismuth.