稀土铝磷酸盐玻璃中镨离子的可见光致发光

Visible Photoluminescence of Praseodymium Ions in Rare-earth Aluminum Phosphate Glass

下载PDF

导出

摘要研究了稀土铝磷酸盐5.8Li2O-3CaO-5BaO-6Al2O3-4.2La2O3-66P2O5(LCBALP)玻璃中镨离子的可见光致发光特性,采用积分球测试系统对其绝对荧光光谱进行表征。1D2→3H4的自发辐射跃迁几率和最大受激发射截面分别为926.5 s-1和3.5×10-21cm2。在蓝色LED激发下,镨离子可见特征发射峰的辐射通量和光通量分别为112.6μW和29.7 mlm,其可见特征发射的总荧光量子产率为4.1%。光学玻璃中镨离子的光谱评估为其在光电子器件和紧凑型照明光源领域的发展提供了重要的参考依据。 Visible photoluminescence properties of praseodymium ions in rare-earth aluminum phosphate 5. 8Li2O-3CaO-5BaO-16Al2O3-4. 2La2O3-66P2O5( LCBALP) glass were investigated and the absolute fluorescence spectra were measured and calibrated in an integrating sphere. The spontaneous emission probability and the maximum stimulated emission cross-section corresponding to the1D2→3H4transition are 926. 5 s- 1and 3. 5 × 10- 21cm2,respectively. Under the blue LED excitation,the radiant flux and the luminous flux for the visible emission bands of LCBALP glass are identified to be 112. 6 μW and 29. 7 mlm,respectively. The total quantum yield for the visible fluorescence is determined to be 4. 1%. The spectral evaluations of praseodymium ions in optical glass provide a reliable reference in developing optoelectronic devices and compact lighting sources.

作者韩晓哲付方方陈宝玖马铁成林海

机构地区大连工业大学纺织与材料工程学院大连海事大学物理系

出处《发光学报》 EI CAS CSCD 北大核心 2013年第10期1306-1312,共7页 Chinese Journal of Luminescence

基金辽宁省自然科学基金(201202011)资助项目

关键词可见光致发光镨离子稀土铝磷酸盐玻璃 visible photoluminescence praseodymium ions rare-earth aluminum phosphate glass

分类号 O482.31 [理学—固体物理]

引文网络
相关文献

参考文献14

1Wei Lü,Zhendong Hao,Xia Zhang,Xingyuan Liu,Xiaojun Wang,Jiahua Zhang.Ca 3 Al 2 (SiO 4 ) 3? δ Cl 4 δ :Eu 2+ , Mn 2+ : A potential phosphor with energy transfer for near-UV pumped white-LEDs[J]Optical Materials,2011(8).
2Jinsu Zhang,Feng Liu,Baojiu Chen,Xiao-jun Wang,Jia-hua Zhang.Parameterizing intensity of 4 f 2 → 4 f 2 electric-dipole transitions in Pr 3+ doped LiYF 4[J]Physics Letters A,2010(3).
3Yuqiu Qu,Xianggui Kong,Yajuan Sun,Qinghui Zeng,Hong Zhang.Effect of excitation power density on the upconversion luminescence of LaF 3 :Yb 3+ , Er 3+ nanocrystals[J]Journal of Alloys and Compounds,2009(1).
4Jiaming Sun,Guozhu Zhong,Xiwu Fan,Guozhu Fu,Chenwei Zheng.Electroluminescence from ITO/SiO 2 /Ta 2 O 5 /Al multiple-layer structure excited by hot electrons[J]Journal of Non-Crystalline Solids,1997(2).
5Ch. Srinivasa Rao,I.V. Kityk,T. Srikumar,G. Naga Raju,V. Ravi Kumar,Y. Gandhi,N. Veeraiah.Spectroscopy features of Pr 3+ and Er 3+ ions in Li 2 O–ZrO 2 –SiO 2 glass matrices mixed with some sesquioxides[J]Journal of Alloys and Compounds,2011(37).
6Jiahua Zhang,Lei Wang,Ye Jin,Xia Zhang,Zhendong Hao,Xiao-jun Wang.Energy transfer in Y 3 Al 5 O 12 :Ce 3+ , Pr 3+ and CaMoO 4 :Sm 3+ , Eu 3+ phosphors[J]Journal of Luminescence,2010(3).
7Liaolin Zhang,Mingying Peng,Guoping Dong,Jianrong Qiu.An investigation of the optical properties of Tb 3+ -doped phosphate glasses for green fiber laser[J]Optical Materials,2012(7).
8Chunyu Zhang,Xingyuan Liu,Li Qin,Wanbin Zhu,Lijun Wang.White microcavity organic light-emitting diode based on one emitting material[J]Journal of Luminescence,2006.
9Dongxu Zhao,Yichun Liu,Dezhen Shen,Jiying Zhang,Youming Lu,Xiwu Fan.The dependence of emission spectra of rare earth ion on the band-gap energy of Mg x Zn 1? x O alloy[J]Journal of Crystal Growth,2002(1).
10Jun Wang,Yaxun Zhou,Shixun Dai,Tiefeng Xu,Qiuhua Nie.State-selective energy transfer from Er 3+ to Eu 3+ in Bi 2 O 3 –GeO 2 –Ga 2 O 3 –Na 2 O glasses[J]Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,2008(1).

二级参考文献57

1辛显双,周百斌,吕树臣,苏文辉.掺铕纳米氧化锌的制备及其发光性质[J].物理学报,2005,54(4):1859-1862. 被引量：15
2孙家跃,石春山,李有谟.低价稀土离子在含氧化合物中的光谱特性及其变化规律——Ⅲ.晶格环境和化学因素对铕(Ⅱ)光谱特性的影响[J].中国稀土学报,1989,7(2):41-46. 被引量：12
3陆晓军,肖志义,张希艳,叶伟光.Eu,Dy共掺铝硼硅酸盐的长余辉发光玻璃[J].发光学报,2005,26(6):819-822. 被引量：7
4刘金霞,吕树臣,李秀明.纳米晶ZrO_2∶Pr^(3+)与ZrO_2∶Pr^(3+),Sm^(3+)发光研究[J].光谱学与光谱分析,2006,26(4):605-609. 被引量：13
5俞莹,吕树臣,周百斌,辛显双.纳米晶ZrO_2:Er^(3+)Yb^(3+)的制备及其室温上转换发射[J].物理学报,2006,55(8):4332-4336. 被引量：12
6杨艳民,陈宝玖,王成,任国仲,王晓君,夏海平.Er^(3+)掺杂的Bi_2O_3-B_2O_3-SiO_2玻璃的光谱性质[J].发光学报,2006,27(4):469-473. 被引量：5
7Reisfeld R,Zelner M,Patra A.Fluorescence study of zirconia films doped by Eu3 +,Tb3 + and Sm3 + and their comparisonwith silica films[J].J.Alloys Compd.,2000,300-301(12):147-151.
8Tanabe S,Hayashi H,Hanada T,et al.Fluorescence properties of Er3+ ions in glass ceramics containing LaF3 nanocrys-tals[J].Opt.Mater.,2002,19(3):343-349.
9Grasser R,Sharmann A,Strack K R.On the intrinsic nature of the blue luminescence in CaWO4[J].J.Lumin.,1982,27(3):263-272.
10Nagirnyi V,Feldbach E,Jonsson L,et al.Excitonic and recombination processes in CaWO4 and CdWO4 scintillators under synchrotron irradiation[J].J.Radiat.Meas.,1998,29(3-4):247-250.

共引文献15

1夏威,张希艳,王细凤,肖志国.Sr_(5-x)(PO_4)_2SiO_4∶xEu^(2+)磷灰石荧光粉的发光性能及LED应用研究[J].发光学报,2013,34(9):1161-1166. 被引量：1
2赵军伟,孔祥贵.氨基磷酸辅助的水热合成NaYF_4∶Yb^(3+),Er^(3+)纳米晶及其上转换发光[J].发光学报,2011,32(7):675-679. 被引量：6
3王雅静,张征,肖林久,谢颖.Dy^(3+)掺杂NaYF_4纳米粒子的制备及其上转换发光性质[J].发光学报,2012,33(3):258-262. 被引量：3
4张影,王如志,王祥夫,曲铭浩,李开宇,颜晓红,严辉.Er:YbF_3转光薄膜的制备及衬底温度对其光学性能的影响[J].发光学报,2012,33(9):979-984. 被引量：1
5陈文威,赵士龙,陈水林,左达先,左伟超,徐时清.Dy^(3+)单掺和Er^(3+),Yb^(3+)共掺氧氟微晶玻璃的发光性能[J].发光学报,2012,33(10):1078-1083. 被引量：2
6郭琬,付方方,杨洁,姜淑文,王志强,林海.紫色发光二极管激发下钐掺杂的重金属硅酸盐玻璃的辐射通量与光通量(英文)[J].发光学报,2013,34(1):49-53. 被引量：1
7金雷,雷小华,任林娇,冯永安,杜晓晴,陈伟民.Eu^(2+)/Dy^(3+)共掺高硅氧发光玻璃发光性质的影响因素分析[J].光谱学与光谱分析,2014,34(1):34-38. 被引量：4
8王博,柏朝晖,常芙嘉.反应pH值对水热法合成PbF_2:Er^(3+),Yb^(3+)荧光粉性能的影响[J].长春理工大学学报（自然科学版）,2014,37(4):48-51.
9李琰,张志华,赵宏伟,何明.Er^(3+)及Er^(3+)/Yb^(3+)掺杂YBa_3B_9O_(18)材料的发光性能[J].大连交通大学学报,2015,36(1):84-87. 被引量：1
10陈清清.Yb^(3+)/Bi^(3+)共掺CaWO_4的制备及近红外发光[J].化工管理,2015(15):217-220.

1王印月,杨映虎,郭永平,王吉政,陈光华,甘润今.埋入SiO_2薄膜中纳米Si的Raman散射和室温可见光致发光[J].科学通报,1997,42(15):1618-1622. 被引量：4
2初本莉,刘行仁,王晓君,张家骅,蒋雪茵.硅酸锶中Pr^(3+)的4f5d态的光谱特性及Pr^(3+)→Gd^(3+)的能量传递[J].发光学报,2001,22(2):187-191. 被引量：2
3张惠奇.PrF3化合物顺磁性的晶场理论[J].华北水利水电学院学报,1993(1):16-20.
4张芳,杨杰慧,潘留占,韩运侠.Pr:YIG中Pr^(3+)离子磁光效应的研究[J].河南师范大学学报（自然科学版）,1999,27(3):29-31.
5张芳,赵治国,杨杰慧.对Pr:YIG中Pr^(3+)离子激发态能级的研究[J].河南大学学报（自然科学版）,2000,30(3):14-16.
6MaHong-Liang LuJiang WangChun-Tao.Measurement of hyperfine structure spectrum in 569.08nm line of ^141Pr^＋[J].Chinese Physics B,2003,12(5):570-570.
7尹华杰,吴建华.无网格法剖析及基扩充EFG法在电磁计算中的应用(英文)[J].计算物理,2004,21(1):68-76.
8陈寒娴,杨瑞东,王茺,邓荣斌,孔令德,杨宇.溅射Si／Ge多层膜及其发光誊性研究[J].功能材料,2008,39(5):730-732. 被引量：2
9佟嵩,刘湘娜,鲍希茂.纳米硅／非晶硅多层膜室温可见光致发光研究[J].Journal of Semiconductors,1995,16(9):716-720.
10贺干武,刘应亮,雷炳富.钙钛矿CaSnO_3∶Pr^(3+)磷光体的发光特性[J].发光学报,2007,28(3):389-392. 被引量：8

发光学报

2013年第10期

浏览历史

内容加载中请稍等...

稀土铝磷酸盐玻璃中镨离子的可见光致发光

参考文献14

二级参考文献57

共引文献15

相关作者

相关机构

相关主题

浏览历史