N-〔2-(2′-氨基-乙氨基)乙基〕草酰胺合铜(Ⅱ)的铜(Ⅱ)-镉(Ⅱ)配合物的合成(英文)

SYNTHESIS OF COPPER(Ⅱ)-CADMIUM(Ⅱ) COMPLEX WITH N-[2-(2'-AMINO-ETHYLAMINO)EHTY1]OXAMIAOCOPPER(Ⅱ)

在水溶液中，通过N－[2－（2'-氨基-乙氨基）乙基]草酰胺和硫酸铜反应，然后再与硫酸镉反应合成了具有草酰胺桥联的新型异核配合物[（phen）Cd3（CuL）：（H2O）3]（SO4）4，其中L配体为N－[2－（2'-氨基-乙氨基）乙基）草酰胺负离子，phen为1，10-邻菲咯啉，测定了配合物的红外光谱，并对其IR的主要吸收进行了归属。

ovel metal complex of the composition [(phen )Cd3 (Cul )2 (H2O)3] (SO4)4to have an extended oxamide-bridged,where L denotes N-[2-(2'-amino-ethylamino)ethyl]oxamido anionand phen denotes 1, 10-phenanthroline,have been synthesized via reaction ofN-[2-(2'-amino-ethylamino)ethyl]oxamide with copper (Ⅱ) Sulfate-5-water and followedreaction with cadmium sulfate in aqueous solution. The IR spectral of the complex wasmeasured and the principal IR bands were assigned.