摘要
Two new inorganic-organic hybrid polymers, Mn(QS)(H<sub>2</sub>O) (1) and Co(QS)(H<sub>2</sub>O)<sub>2</sub> (2) (H<sub>2</sub>QS=8-hydroxylquinoline-5-sulfonic acid), based on 8-hydroxylquinoline-5-sulfonate ligand, have been synthesized under solvothermal conditions and their structures were solved by single-crystal X-ray diffraction analysis. Compound 1 is a three-dimensional open framework with rutile topology structure, and compound 2 is a three-dimensional supramolecular structure. These compounds were characterized by powder XRD, infrared spectroscopy, thermogravimetric analysis, fluorescence properties and magnetism properties.
Two new inorganic-organic hybrid polymers, Mn(QS)(H2O) (1) and Co(QS)(H2O)2 (2) (H2QS=8-hydroxyl-quinoline-5-sulfonic acid), based on 8-hydroxylquinoline-5-sulfonate ligand, have been synthesized under solvothermal conditions and their structures were solved by single-crystal X-ray diffraction analysis. Compound 1 is a three-dimensional open framework with rutile topology structure, and compound 2 is a three-dimensional supramolecular structure. These compounds were characterized by powder XRD, infrared spectroscopy, thermogravimetric analysis, fluorescence properties and magnetism properties.
基金
Supported by the State Basic Research Project (2006CB806100)
Outstanding Young Scientist Foundation of the National Natural Science Foundation of China (20625102)
the National Natural Science Foundation of China (Grant Nos. 20831D02, 20571030, 20531030, and 20371020)
"111" Program of Ministry of Education of China and Bureau of Science & Technology of Jilin Province
Jilin Province Hi-Tech Development Project (20090131)
International Cooperation Project of Ministry of Science and Technology (2007DFA40830)
