摘要
From readily available propargylic carboxylates, two sequential transformations―gold-catalyzed tandem reactions and Sc(OTf)3-catalyzed cyclization―in a one-pot process led to the formation of 2-acylcyclohexenones with an electron-rich arene ring fused at the 4,5-positions.
From readily available propargylic carboxylates, two sequential transformations—gold-catalyzed tandem reactions and Sc(OTf)3-catalyzed cyclization—in a one-pot process led to the formation of 2-acylcyclohexenones with an electron-rich arene ring fused at the 4,5-positions.
基金
Supported by the NSF of USA (CAREER award CHE-0748484) and UNR