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One-pot synthesis of arene-fused 2-acylcyclohexenones from propargylic carboxylates

One-pot synthesis of arene-fused 2-acylcyclohexenones from propargylic carboxylates
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摘要 From readily available propargylic carboxylates, two sequential transformations―gold-catalyzed tandem reactions and Sc(OTf)3-catalyzed cyclization―in a one-pot process led to the formation of 2-acylcyclohexenones with an electron-rich arene ring fused at the 4,5-positions. From readily available propargylic carboxylates, two sequential transformations—gold-catalyzed tandem reactions and Sc(OTf)3-catalyzed cyclization—in a one-pot process led to the formation of 2-acylcyclohexenones with an electron-rich arene ring fused at the 4,5-positions.
出处 《Science China Chemistry》 SCIE EI CAS 2009年第9期1337-1344,共8页 中国科学(化学英文版)
基金 Supported by the NSF of USA (CAREER award CHE-0748484) and UNR
关键词 gold REARRANGEMENT CYCLIZATION catalysis LEWIS acid gold rearrangement cyclization catalysis Lewis acid
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