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Research on polyfluorene derivatives end-capped by N-hexyl-carbazole and benzene 被引量:1

Research on polyfluorene derivatives end-capped by N-hexyl-carbazole and benzene
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摘要 Copolymers of 9,9-dioctylfluorene (DOF) and 2-thienyl-benzothiadiazole (DBT) were synthesized by Suzuki reaction and end-capped by N-hexyl-carbazole and benzene, which were abbreviated as PDOF-DBT-Cz and PDOF-DBT-B, respectively. The photophysical, electrochemical and thermal properties of the copolymers were studied. The results indicated that replacement of N-hexyl-carbazole as end-capping group of PDOF-DBT can vary light color and improve luminescence efficiency. Copolymers of 9,9-dioctylfluorene (DOF) and 2-thienyl-benzothiadiazole (DBT) were synthesized by Suzuki reaction and end-capped by N-hexyl-carbazole and benzene, which were abbreviated as PDOF-DBT-Cz and PDOF-DBT-B, respectively. The photophysical, electrochemical and thermal properties of the copolymers were studied. The results indicated that replacement of N-hexyl-carbazole as end-capping group of PDOF-DBT can vary light color and improve luminescence efficiency.
出处 《Science China(Technological Sciences)》 SCIE EI CAS 2009年第8期2190-2194,共5页 中国科学(技术科学英文版)
基金 Supported by the Major Project of Science Foundation Ministry of Education of China (Grant No. 207015) the National Natural Science Foundation of China (Grant No. 20671068)
关键词 FLUORENE CARBAZOLE END capping MATERIAL fluorene carbazole end capping material
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