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正丁醇-乙酸丁酯-1-辛基-3-甲基咪唑六氟磷酸盐的等压汽-液和液-液相平衡

Vapor-liquid equilibrium and liquid-liquid equilibrium of n-butanol+n-butyl acetate+1-octyl-3-methylimidazolium hexafluorophosphate
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摘要 测定了101.3 kPa下正丁醇-乙酸丁酯-1-辛基-3-甲基咪唑六氟磷酸盐([OMIM][PF_6])体系的液-液平衡和汽-液平衡,并用NRTL方程对测得的液液平衡数据进行了关联,得到方程的二元参数。用液液平衡所得到的NRTL方程二元参数,预测了正丁醇-乙酸丁酯-[OMIM][PF_6]体系的汽-液平衡,预测结果和汽-液平衡实验结果吻合良好。实验表明[OMIM][PF_6]能够增加正丁醇对乙酸丁酯的相对挥发度,消除丁醇-乙酸丁酯共沸点,且随着[OMIM][PF_6]含量的增加,正丁醇对乙酸丁酯的相对挥发度增大。 测定了101.3 kPa下正丁醇-乙酸丁酯-1-辛基-3-甲基咪唑六氟磷酸盐([OMIM][PF<sub>6</sub>])体系的液-液平衡和汽-液平衡,并用NRTL方程对测得的液液平衡数据进行了关联,得到方程的二元参数。用液液平衡所得到的NRTL方程二元参数,预测了正丁醇-乙酸丁酯-[OMIM][PF<sub>6</sub>]体系的汽-液平衡,预测结果和汽-液平衡实验结果吻合良好。实验表明[OMIM][PF<sub>6</sub>]能够增加正丁醇对乙酸丁酯的相对挥发度,消除丁醇-乙酸丁酯共沸点,且随着[OMIM][PF<sub>6</sub>]含量的增加,正丁醇对乙酸丁酯的相对挥发度增大。
出处 《化工进展》 EI CAS CSCD 北大核心 2011年第S2期15-19,共5页 Chemical Industry and Engineering Progress
关键词 液-液平衡 汽-液平衡 正丁醇 乙酸丁酯 离子液体 liquid-liquid equilibrium vapor-liquid equilibrium n-butanol n-butyl acetate ionic liquid
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参考文献17

  • 1Arce A,Rodriguez H,Soto A.Effect of anion fluorination in 1 ethyl-3-methylimidazolium as solvent for the liquid extraction of ethanol from ethyl tert-butyl ether. Fluid Phase Equilibria . 2006
  • 2Arce A,Rodriguez H,Soto A.Purification of ethyl tert-butyl ether from its mixtures with ethanol by using an ionic liquid. Chemical Engineering . 2006
  • 3Lin S T,Sandler S 1.A priori phase equilibrium prediction from a segment contribution solvation model. Industrial and Engineering Chemistry . 2002
  • 4Cai J L,,Cui X B,Zhang Y.et al.Vapor-liquid equilibrium and liquid-liquid equilibrium of methyl acetate +,methanol + 1-ethyl-3-methylimidazolium acetate. Journal of Chemical Engineering Data . 2011
  • 5Kato R,Krummen M,Gmehling J.Measurement and correlation of vapor-liquid equilibria and excess enthalpies of binary systems containing ionic liquids and hydrocarbons. Fluid Phase Equilibria . 2004
  • 6Orchilles A V,Miguel P J,et al.Ionic liquids as entrainers in extractive distillation:Isobaric vapor-liquid equilibria for acetone + methanol 4- 1-ethyl-3-methylimidazolium trifluoromethanesulfonate. Journal of Chemical Engineering Data . 2007
  • 7Freemantle M.Ionic liquids show promise for clean separation technology. Chemical and Engineering News . 1998
  • 8Kraemer K,Kossack,S,Marquardt,W."Efficient optimization-based design of distillation processes for homogenous azeotropic mix-tures". Industrial and Engineering Chemistry Research . 2009
  • 9Widagdo,S.,Seider,W. D.Azeotropic Distillation. American Institute of Chemical Engineers Journal . 1996
  • 10C Hardacre,JD Holbrey,M Nieuwenhuyzen,TGA Youngs.Structure and Solvation in Ionic Liquids. Accounts of Chemical Research . 2007

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