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Photocatalytic Degradation of Metronidazole in Aqueous Solution by Niobate K_6Nb_(10.8)O_(30) 被引量:2

Photocatalytic Degradation of Metronidazole in Aqueous Solution by Niobate K_6Nb_(10.8)O_(30)
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摘要 The photocatalytic degradation of antibiotic metroni-dazole in aqueous solution by niobate K6Nb10.8O30 photocatalyst that was prepared using a soft-chemical method was studied by Fourier transform infrared spectroscopy and UV-Vis absorption spectrum. Metronidazole is very stable and is difficult to degrade under UV irradiation. K6Nb10.8O30 photocatalyst cannot degrade metronidazole without UV irradiation and shows very high photo-catalytic activity for the degradation of metronidazole under UV irradiation. The photocatalytic degradation rate of metronidazole increased with increasing the dosage of K6Nb10.8O30 photocatalyst. The photocatalytic degradation reaction of metronidazole by nio-bate K6Nb10.8O30 follows the first-order kinetic equation. The photocatalytic degradation of antibiotic metroni-dazole in aqueous solution by niobate K6Nb10.8O30 photocatalyst that was prepared using a soft-chemical method was studied by Fourier transform infrared spectroscopy and UV-Vis absorption spectrum. Metronidazole is very stable and is difficult to degrade under UV irradiation. K6Nb10.8O30 photocatalyst cannot degrade metronidazole without UV irradiation and shows very high photo-catalytic activity for the degradation of metronidazole under UV irradiation. The photocatalytic degradation rate of metronidazole increased with increasing the dosage of K6Nb10.8O30 photocatalyst. The photocatalytic degradation reaction of metronidazole by nio-bate K6Nb10.8O30 follows the first-order kinetic equation.
出处 《Wuhan University Journal of Natural Sciences》 CAS 2010年第4期345-349,共5页 武汉大学学报(自然科学英文版)
基金 Supported by Program for New Century Excellent Talents in University (NCET05-0662)
关键词 NIOBATE potassium niobate METRONIDAZOLE photo- catalytic KINETICS niobate potassium niobate metronidazole photo- catalytic kinetics
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  • 1熊振湖,陈在旭,刘建明.不同高级氧化法对水中低浓度药物甲硝唑降解过程的比较[J].环境工程学报,2009,3(3):465-469. 被引量:7
  • 2杨陈,杨昌军,法文君,龚楚清,彭天右,昝菱.单质碘掺杂纳米TiO_2光催化剂的制备及性能[J].武汉大学学报(理学版),2008,54(6):645-649. 被引量:5
  • 3郑志军,王奎涛,张炳烛,高金龙,吴海霞,刘燕.二氧化氯催化氧化处理医药废水[J].河北化工,2008,31(12):76-78. 被引量:4
  • 4刘华俊,彭天右,彭正合,戴珂.Dy/WO_3光催化降解罗丹明B的反应机理[J].武汉大学学报(理学版),2007,53(2):127-132. 被引量:34
  • 5Ye J H,,Zou Z G,Matsushita A.A novel series of water split- ting photocatalysts NiM2O6 (M = Nb, Ta) active under visible light. International Journal of Hydrogen Energy . 2003
  • 6Zou Z G,Ye J H,Arakawa H.Structural properties of InNbO4 and InTaO4: correlation with photocatalytic and photophysical properties. The Journal of Chemical Physics . 2003
  • 7He C H,Gu M Y.Photocatalytic activity of bismuth germa- nate Bi12GeO20 powders. Scripta Materialia . 2006
  • 8Sleiman M,Conchon P,Ferronato C, et al.Iodosulfuron deg- radation by TiO2 photocatalysis: Kinetic and reactional path- way investigations. Applied Catalysis . 2007
  • 9Talebian N,Nilforoushan M R.Comparative study of the structural, optical and photocatalytic properties of semicon- ductor metal oxides toward degradation of methylene blue. Thin Solid films . 2010
  • 10Saiena J,Asgari M,Soleymani A R, et al.Photocatalytic de- composition of direct red 16 and kinetics analysis in a conic body packed bed reactor with nanostructure titania coated Raschig rings. Chemical Engineering . 2009

二级参考文献41

  • 1刘华俊,彭天右,肖江蓉,赵德,彭正合.Tb^(3+)掺杂纳米WO_3的制备及其光催化性能[J].武汉大学学报(理学版),2005,51(4):397-401. 被引量:15
  • 2张德莉,黄应平,罗光富,刘德富,马万红,赵进才.Fenton及Photo-Fenton反应研究进展[J].环境化学,2006,25(2):121-127. 被引量:100
  • 3何苗,张晓健,瞿福平,顾夏声.焦化废水中芳香族有机物及杂环化合物在活性污泥法处理中的去除特性[J].中国给水排水,1997,13(1):14-17. 被引量:71
  • 4Woo S H,Kim W W,Kim SJ,etal. Photocatalytic Behaviors of Transition Metal Ion Doped TiO2 Powder Synthesized by Mechanical Alloying [J]. Marterials Science and Engineering A, 2007,449 : 1151-1154.
  • 5Fujishima A, Honda K. Electrochemical Photolysis of Water at a Semiconductor Electrode[J]. Nature, 1972, 233:37-38.
  • 6Vinodgopal K,Kamat P V. Enhanced Rates of Photo- catalytic Degradation of an Azo Dye Using SnO2/TiO2 Coupled Semiconductor Thin Films [J]. Environmental Science Technology, 1995,29(3) : 841-845.
  • 7Torres C E R,Golmar F,Cabrera A F,etal. Magnetic and Structural Study of Cu-Doped TiO2 Thin Films [J]. Applied Surface Science, 2007,254(1) : 365-367.
  • 8Tanahashi I. Photocatalytic Preparation of Ag/TiO2 Films and Their Localized Surface Plasmon Resonance Sensing Properties[J]. Bulletin of the Chemical Society of Japan ,2007,80(10) :2019-2023.
  • 9Dyrbeck H, Hammer N, Ronning M, et al. Catalytic Oxidation of Hydrogen over Au/TiO2 Catalysts[J].Topics in Catalysis ,2007,45(1-4) : 21-24.
  • 10Nakano Y, Morikawa T, Ohwaki T, et al. Origin of Visible-light Sensitivity in N-Doped TiO2 Films[J]. Chemical Physics, 2007,339 (1-3) : 36-42.

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