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[Cu(en)_2][KFe(CN)_6]·H_2O的磁性分析

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摘要 合成了氰根桥联配合物[[Cu(en)2][KFe(CN)6].H2O,使用元素分析、红外光谱等对配合物进行了表征。首次通过对该配合物的磁化率测定表明金属离子通过氰根传递弱反铁磁作用,计算求得分子磁体χmT的实验值与理论值。并根据Curie-Weiss定律拟合获得居里常数C=0.42cm3.K.mol-1和顺磁居里温度=-0.54K。
出处 《广西物理》 2010年第1期19-22,共4页 Guangxi Physics
基金 广西自然科学基金项目(0991092) 广西研究生教育创新项目((2009106020702M39 2008106020702M240)
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  • 1寇会忠,廖代正.一种设计实用分子铁磁体的有效构件——普鲁士蓝类配合物[J].无机化学学报,1999,15(2):141-150. 被引量:15
  • 2S Shin-ichi Ohkoshi,Kazuhito Hashimoto.Design of a Novel Magnet Exhibiting Photoinduced Magnetic Pole Inversion Based on Molecular Field Theory. Journal of the American Chemical Society . 1999
  • 3Kenneth Van Langenberg,David C.R.Hockless,Boujemaa Moubaraki,et al.Long-range magnetic order displayed by a bimetallic pentanuclearcluster complex[ (Ni (2’2-bipy)2)3 (Fe (CN)6)2].13H2Oandby a Cu (II)analog. Synthetic Metals . 2001
  • 4K.Chandra,D.Raj,S.P.Puri.M?ssbauer Studies of Ferro-and Ferricyanide Superco-mplexes with 3d Transition Elements. The Journal of Chemical Physics . 1967
  • 5S.Iijima,Z.Honda,S.Koner,et al.Magnetic and M?ssbauer studies of cyanide-bridged bimetallic assembly[Mn (cyclam)][Fe (CN)6].3H2O. J.Magn.Magn.Mater . 2001
  • 6Alivisatos A P,Barbara P F,Castleman A W,et al.From molecules to materials: current trends and future directions. Advanced Materials . 1998
  • 7Mallah T,Thiebaut S,Verdaguer M,et al.High-Tc Molecular-Based Magnets: Ferrimagnetic Mixed-Valence Chromium(Ⅲ )-Chromium(Ⅱ ) Cyanides with Tc at 240 and 190 Kelvin. Science . 1993
  • 8Sato O,Iyoda T,Fujishima A,et al.Electrochemically tunable magnetic phase transition in a high-Tc chromium cyanide thin film. Science . 1996
  • 9Ferlay S,Mallah T,Ouahes R,et al.A room-temperature organometallic magnet based on Prussian blue. Nature . 1995
  • 10Ohba M,Okawa H.Synthesis and Magnetism of Multi-dimensional Cyanide-bridged Bimetallic Assemblies. Coordination Chemistry Reviews . 2000

二级参考文献1

  • 1缪明明,Sci Technol Herald,1994年,7卷,29页

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