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Catalytic pyrolysis of Pubescens to phenols over Ni/C catalyst 被引量:4

Catalytic pyrolysis of Pubescens to phenols over Ni/C catalyst
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摘要 The pyrolysis of Pubescens over Ni/C catalyst was studied at 350°C in H2 flow.The presence of Ni/C catalyst efficiently improved the degradation of raw materials,and produced bio-oil with high content of phenols but low contents of acetic acid,furfural and water.In the reaction,Ni/C catalyst plays the role of catalytic decomposition and catalytic hydrogenation.The existence of the carbon carrier favors the formation of active Ni in small sizes with more defects,which results in high catalytic activity of Ni in biomass decomposition and selective production of phenols. The pyrolysis of Pubescens over Ni/C catalyst was studied at 350°C in H2 flow.The presence of Ni/C catalyst efficiently improved the degradation of raw materials,and produced bio-oil with high content of phenols but low contents of acetic acid,furfural and water.In the reaction,Ni/C catalyst plays the role of catalytic decomposition and catalytic hydrogenation.The existence of the carbon carrier favors the formation of active Ni in small sizes with more defects,which results in high catalytic activity of Ni in biomass decomposition and selective production of phenols.
出处 《Science China Chemistry》 SCIE EI CAS 2010年第7期1487-1491,共5页 中国科学(化学英文版)
基金 supported by the National Basic Research Program of China (2007CB210203) the Special Research Fund for the Doctoral Program of Higher Education of China (20050610013)
关键词 Ni/C catalyst Pubescens catalytic pyrolysis PHENOLS Ni/C catalyst Pubescens catalytic pyrolysis phenols
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  • 1刘文武,胡常伟,杨宇,祝良芳,童冬梅.HY分子筛催化剂作用时机对毛竹热解的影响(英文)[J]Chinese Journal of Chemical Engineering,2010(02).
  • 2陆强,朱锡锋,李全新,郭庆祥,朱清时.生物质快速热解制备液体燃料[J].化学进展,2007,19(7):1064-1071. 被引量:38
  • 3苗霞,罗嘉,李桂英,胡常伟.毛竹在氢气中的催化热解研究[J].化学研究与应用,2007,19(5):507-512. 被引量:6
  • 4Lin YC,Huber GW.The critical role of heterogeneous catalysis in lignocellulosic biomass conversion. Energy Environ Sci . 2009
  • 5Zhang YH,Wang AQ,Zhang T.A new 3D mesoporous carbon rep- licated from commercial silica as a catalyst support for direct conver- sion of cellulose into ethylene glycol. Chemical Communications . 2010
  • 6Atul S,Ikuo S,Hiroyuki N,Kouichi M.Effect of carbonization tem- perature on the nickel crystallite size of a Ni/C catalyst for catalytic hydrothermal gasification of organic compounds. Fuel . 2007
  • 7Basagiannis AC,Verykios XE.Reforming reactions of acetic acid on nickel catalysts over a wide temperature range. Applied Catalysis A General . 2006
  • 8Furimsky E.Catalytic hydrodeoxygenation. Applied Catalysis A General . 2000
  • 9Elliott DC,Hart TR.Catalytic hydroprocessing of chemical models for bio-oil. Energ Fuel . 2009
  • 10D.Mohan.,C.U.Pittman,,P.H.Steele.Pyrolysis of Wood/Biomass for Bio-oil:A Critical Review. Energy and Fuels . 2006

二级参考文献55

  • 1杜瑛,齐卫艳,苗霞,李桂英,胡常伟.毛竹的主要化学成分分析及热解[J].化工学报,2004,55(12):2099-2102. 被引量:31
  • 2汪俊锋,常杰,阴秀丽,付严.生物质气催化合成甲醇的研究[J].燃料化学学报,2005,33(1):58-61. 被引量:27
  • 3张琦,常杰,王铁军,徐莹.生物质裂解油的性质及精制研究进展[J].石油化工,2006,35(5):493-498. 被引量:42
  • 4朱锡锋,陆强,郑冀鲁,郭庆祥,朱清时.生物质热解与生物油的特性研究[J].太阳能学报,2006,27(12):1285-1289. 被引量:78
  • 5胡常伟.NaY分子筛催化毛竹热解液化研究,见:吴创之,袁振宏,易维明等.2005年中国生物质能技术与可持续发展研讨会论文集,广州:太阳能学会生物质能专业委员会,2005,144~120
  • 6Weiyan Qi,Changwei Hu,Guiying Li,et al.Catalytic pyrolysis of several kinds of bamboos over zeolite NaY[J].Green Chemistry,2006,8:183-190.
  • 7Sutton D,Kelleher B,Ross J R H.Review of literature on catalysts for biomass gasification[J].Fuel Process Technol,2001,73:155-173.
  • 8Hall D O,Rosillo-Calle F,de Groot P.Biomass energy lessons from case studies in developing countries[J].Energ Policy,1992,20:62-73.
  • 9Zhongyang Luo,Shurong Wang,Yanfen Liao,et al.Research on Biomass Fast Pyrolysis for Liquid Fuel[J].Biomass Bioenergy,2004,26 (5):455-462.
  • 10Yang Y F,Feng C P,Inamori Y,et al.Analysis of energy conversion characteristics in liquefaction of algae[J].Resour Conserv Recy,2004,43:21-33.

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