摘要
Triarylboron compounds are significant optoelectronic materials due to their excellent emissive and electron-transport properties,and could be applied in organic light-emitting diodes as emissive and/or electron-transport layers.Triarylboron compounds have vacant pπ orbital and have received increasing interest as fluoride ion and cyanide ion sensors utilizing specific Lewis acid-base interaction.This review summarizes their structural characteristics,optical properties and applications in chemosensors for anions and optoelectronic devices developed in recent years and discusses the problems and prospects.
Triarylboron compounds are significant optoelectronic materials due to their excellent emissive and electron-transport properties,and could be applied in organic light-emitting diodes as emissive and/or electron-transport layers.Triarylboron compounds have vacant pπ orbital and have received increasing interest as fluoride ion and cyanide ion sensors utilizing specific Lewis acid-base interaction.This review summarizes their structural characteristics,optical properties and applications in chemosensors for anions and optoelectronic devices developed in recent years and discusses the problems and prospects.
作者
MOU Xin1,LIU ShuJuan1,DAI ChunLei1,MA TingChun1,ZHAO Qiang1,2,LING QiDan1 & HUANG Wei1 1Key Laboratory for Organic Electronics & Information Displays (KLOEID) and Institute of Advanced Materials (IAM),Nanjing University of Posts and Telecommunications,Nanjing 210046,China
2State Key Laboratory of Coordination Chemistry,Nanjing University,Nanjing 210093,China
基金
supported by the National Basic Research Program of China (973 Program, 2009CB930601)
the National Natural Science Foundation of China (50803028, 20804019, 20774043 & 60976019)
Program for New Century Excellent Talents in University (NCET-07-0446)
Natural Science Foundation of Jiangsu Province of China (BK2009427)
Natural Science Fund for Colleges and Universities in Jiangsu Province (08KJD430017)
Scientific and Technological Innovation Teams of Colleges and Universities in Jiangsu Province (TJ207035)
Scientific and Technological Activities for Returned Personnel in Nanjing City (NJ209001 & TJ208027)
Nanjing University of Posts and Telecommunications (NY208045 & NY207161)
Program for Postgraduates Research Innovation of Colleges and Universities in Jiangsu Province (CX09S_011Z)