摘要
Phosphonium or arsonium salt with primary alcohol can undergo the tandem reaction of deprotonation-oxidation-Wittig reaction in the presence of sodium hydroxide and manganese dioxide, providing a general and efficient method for the stereoselective synthesis of (E) -α, β-unsaturated enoates.
Phosphonium or arsonium salt with primary alcohol can undergo the tandem reaction of deprotonation-oxidation-Wittig reaction in the presence of sodium hydroxide and manganese dioxide, providing a general and efficient method for the stereoselective synthesis of (E) -α, β-unsaturated enoates.
基金
theNationalNaturalScienceFoundationofChina (No.2 9972 0 36 )