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Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction: Stereoselective Synthesis of (E)-α,β-Unsaturated Enoates

Tandem Reaction of Deprotonation-Oxidation-Wittig Reaction: Stereoselective Synthesis of (E)-α,β-Unsaturated Enoates
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摘要 Phosphonium or arsonium salt with primary alcohol can undergo the tandem reaction of deprotonation-oxidation-Wittig reaction in the presence of sodium hydroxide and manganese dioxide, providing a general and efficient method for the stereoselective synthesis of (E) -α, β-unsaturated enoates. Phosphonium or arsonium salt with primary alcohol can undergo the tandem reaction of deprotonation-oxidation-Wittig reaction in the presence of sodium hydroxide and manganese dioxide, providing a general and efficient method for the stereoselective synthesis of (E) -α, β-unsaturated enoates.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2002年第11期1460-1462,1136,共0页 中国化学(英文版)
基金 theNationalNaturalScienceFoundationofChina (No.2 9972 0 36 )
关键词 phosphonium or arsonium salt alcohol YLIDE α β-unsaturated enoate synthesis DEPROTONATION oxidation Wittig reaction tandem reaction phosphonium or arsonium salt alcohol ylide α,β-unsaturated enoate synthesis deprotonation oxidation Wittig reaction tandem reaction
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