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NO_x emission from incineration of organic hazardous liquid waste containing hexamethylendiamine in fluidized bed

NO_x emission from incineration of organic hazardous liquid waste containing hexamethylendiamine in fluidized bed
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摘要 Experiments have been conducted to investigate  NO x concentration profiles along bed height and influences of temperature and excess air on  NO x emission in the range from 700 ℃ to 900 ℃, when waste water containing 5% Hexamethylenediamine incinerated in a bench scale hot fluidized bed. The testing results indicate that the concentration of NO 2 is larger than that of NO along bed height except in the freeboard at 900 ℃, where NO, NO 2 concentrations are zero. Temperature and excess air play significant role on  NO x emission. With increasing in temperature the  NO x emission decreases very rapidly in the range from 700 ℃ to 900 ℃. With increasing in excess air,  NO x emission increases considerably at 700 ℃, but it is almost independent of excess air at 800 ℃,and at 900 ℃  NO x emission is zero indicating that NH 2 from NH 2(CH 2) 6NH 2 has strong effect on de  NO x with increasing in temperature and excess air.  NO x concentration profiles decrease progressively with bed height because of reduction of  NO x by NH 2. The mechanism of  NO x formation and destruction is presented in the paper. Experiments have been conducted to investigate  NO x concentration profiles along bed height and influences of temperature and excess air on  NO x emission in the range from 700 ℃ to 900 ℃, when waste water containing 5% Hexamethylenediamine incinerated in a bench scale hot fluidized bed. The testing results indicate that the concentration of NO 2 is larger than that of NO along bed height except in the freeboard at 900 ℃, where NO, NO 2 concentrations are zero. Temperature and excess air play significant role on  NO x emission. With increasing in temperature the  NO x emission decreases very rapidly in the range from 700 ℃ to 900 ℃. With increasing in excess air,  NO x emission increases considerably at 700 ℃, but it is almost independent of excess air at 800 ℃,and at 900 ℃  NO x emission is zero indicating that NH 2 from NH 2(CH 2) 6NH 2 has strong effect on de  NO x with increasing in temperature and excess air.  NO x concentration profiles decrease progressively with bed height because of reduction of  NO x by NH 2. The mechanism of  NO x formation and destruction is presented in the paper.
出处 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2002年第1期24-28,共5页 哈尔滨工业大学学报(英文版)
关键词 fluidized BED INCINERATION LIQUID WASTE NO x EMISSION fluidized bed incineration liquid waste  NO x emission
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参考文献5

  • 1MILLER J A,BOWMAN C T.Mechanism and modeling of Nitrogen chemistry in combustion[].Progress in Energy and Combustion Science.1989
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  • 5SALIMIAN S,HANSON R K.A kinetic study of NO removal from combustion gases by injection of NH i-containing compounds combustion[].Science and Technology.1980

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