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Chemiluminescence Determination of Thiourea Using Tris(1,10-phenanthroline)-ruthenium(Ⅱ) -KMnO_4 System

Chemiluminescence Determination of Thiourea Using Tris(1,10-phenanthroline)-ruthenium(Ⅱ) -KMnO_4 System
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摘要 The light emission produced by thiourea in oxidation process by permanganate in acidic solution in the presence of Ru(phen) 2+ 3 is used to determine 1.0×10 -8 \|1.0×10 -5 mol/L thiourea. The limit of detection is 9.8×10 -9 mol/L and the relative standard deviation is 1.1% for a 1.0×10 -5 mol/L thiourea solution ( n =10). The method was applied satisfactorily to the determination of thiourea. The light emission produced by thiourea in oxidation process by permanganate in acidic solution in the presence of Ru(phen) 2+ 3 is used to determine 1.0×10 -8 \|1.0×10 -5 mol/L thiourea. The limit of detection is 9.8×10 -9 mol/L and the relative standard deviation is 1.1% for a 1.0×10 -5 mol/L thiourea solution ( n =10). The method was applied satisfactorily to the determination of thiourea.
出处 《Wuhan University Journal of Natural Sciences》 CAS 2002年第3期341-344,共4页 武汉大学学报(自然科学英文版)
基金 SupportbyMinistryofEducation WuhanUniversityandAlumniAssociationofit
关键词 THIOUREA CHEMILUMINESCENCE tris(1 10 phenanthroline)ruthenium(Ⅱ) Thiourea chemiluminescence tris(1,10 phenanthroline)ruthenium(Ⅱ)
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  • 1Nj. Radi?,J. Komljenovi?.Potentiometric determination of mercury(II) and thiourea in strong acid solution using an ion-selective electrode with AgI-based membrane hydrophobised by PTFE[J].Fresenius’ Journal of Analytical Chemistry.1991(10)

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