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On the role of ketone in the tribological behaviour of zinc dialkyldithiophosphate

On the role of ketone in the tribological behaviour of zinc dialkyldithiophosphate
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摘要 This study reports the influence of methyl isopropyl ketone, which often kept in com-mercial zinc dialkyldithiophosphate (ZDDP) as a residue, on the tribological performance of ZDDP.The lubricity test of 500 SN neutral base stock oil containing ZDDP with methyl isopropyl ketonewas carried out by MQ--800 four-ball thbometer. The experimental results show that the methylisopropyl ketone results in the decrement of the wear resistance of ZDDP. The ketone compounddecreases greatly the load-carry capacity of ZDDP. The fact that the antiwear performance ofZDDP reduces with the addition of methyl isopropyl ketone could be partly attributed to a nucleo-philic substitution reaction, which retards the formation of phosphate antiwear films. This study reports the influence of methyl isopropyl ketone, which often kept in com- mercial zinc dialkyldithiophosphate (ZDDP) as a residue, on the tribological performance of ZDDP. The lubricity test of 500 SN neutral base stock oil containing ZDDP with methyl isopropyl ketone was carried out by MQ--800 four-ball thbometer. The experimental results show that the methyl isopropyl ketone results in the decrement of the wear resistance of ZDDP. The ketone compound decreases greatly the load-carry capacity of ZDDP. The fact that the antiwear performance of ZDDP reduces with the addition of methyl isopropyl ketone could be partly attributed to a nucleo- philic substitution reaction, which retards the formation of phosphate antiwear films.
出处 《Science China Mathematics》 SCIE 2001年第S1期171-176,共6页 中国科学:数学(英文版)
关键词 KETONE ZINC dialkyldithiophosphate ZDDP TRIBOLOGICAL PERFORMANCE ketone zinc dialkyldithiophosphate ZDDP tribological performance
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参考文献2

  • 1M.L. Suominen Fuller,L. Rodriguez Fernandez,G.R. Massoumi,W.N. Lennard,M. Kasrai,G.M. Bancroft.The use of X‐ray absorption spectroscopy for monitoring the thickness of antiwear films from ZDDP[J].Tribology Letters.2000(4)
  • 2Jean Michel Martin.Antiwear mechanisms of zinc dithiophosphate: a chemical hardness approach[J].Tribology Letters.1999(1)

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