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Thermodynamic analysis on synthesis process of diamond

Thermodynamic analysis on synthesis process of diamond
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摘要 Based upon the thermodynamic analysis of the nucleation of d iamond crystal, the effects of synthesis temperature and pressure on the nucleat ion of diamond crystal, diamond growth and output of diamond crystal, particle s ize and strength were discussed. The results show that the excess pressure has a n important effect on the critical radius of nucleation and thermodynamic b a rrier in the formation of a critical nucleus. Considering the excess pressure, t he expression of diamond nucleation rate was obtained. Based upon the thermodynamic analysis of the nucleation of diamond crystal, the effects of synthesis temperature and pressure on the nucleation of diamond crystal, diamond growth and output of diamond crystal, particle size and strength were discussed. The results show that the excess pressure has an important effect on the critical radius of nucleation and thermodynamic barrier in the formation of a critical nucleus. Considering the excess pressure, the expression of diamond nucleation rate was obtained.
出处 《Journal of Central South University》 SCIE EI CAS 2001年第3期156-160,共5页 中南大学学报(英文版)
基金 TheFoundationforUniversityOutstandingTeacheroftheMinistryofEducation
关键词 DIAMOND SYNTHESIS PRESSURE TEMPERATURE NUCLEATION GR owth Key words diamond synthesis pressure temperature nucleation growth
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参考文献11

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