摘要
In this article VLE data for a ternary system (propylene-methanol-water) under 30~60 C,0. 3~0. 9 MPa with a mass ratio of methanol to water of 9:1, 8: 2, 7: 3 were determined with a static equilibrium still, and were correlated by using Peng-Robinson model. The average relative error ofpropylene concentration in liquid phase is 1. 46 %. The results indicate that the models are very suitablefor the ternary system and the data are reliable.
用静态平衡釜法测定丙烯-水-甲醇三元物系在30~60C,0.3~0.9MPa下,甲醇-水比例为9∶1、8∶2、7∶3时的汽液平衡数据,用Peng-Robinson模型方程对汽液平衡数据进行了关联,求得各模型参数,其中液相丙烯的平均相对偏差为1.46%。