摘要
New boronoalkoxycalix[4] arenes were synthesized by allylation, alkylation, hydroboration and hydrolysis of 25,26,27,28-tetraydroxycalix[4] arene, and identified by elemental analysis, IR, 1H NMR, 13C NMR, 11B NMR, Ms and UV spectra. The data of UV and fluorescence spectra showed that tetrapropoxycalix-[4]arene triboronic acid could coordinate significantly with monosaccharides.
New boronoalkoxycalix[4] arenes were synthesized by allylation, alkylation, hydroboration and hydrolysis of 25,26,27,28-tetraydroxycalix[4] arene, and identified by elemental analysis, IR, 1H NMR, 13C NMR, 11B NMR, Ms and UV spectra. The data of UV and fluorescence spectra showed that tetrapropoxycalix-[4]arene triboronic acid could coordinate significantly with monosaccharides.
基金
Project supported by the National Natural Science Foundation of China (29872034)
the Natural Science Foundation of Henan Province.
