摘要
In-situ synthesis of terbium complex with salicylic acid (Sal) in silica matrix was made by a two-step sol-gel process. The terbium complex with salicylic acid was formed in sol-gel derived silica gel, and confirmed by the luminescence excitation spectra and infrared (IR) spectra. As compared with the pure terbium complex powder, the silica gel containing terbium complex exhibits its characteristic emission and presents a longer fluorescence lifetime than that for the pure complex. The luminescence properties of the complex containing silica gel were investigated and compared with those of both terbium doped the silica gel and the pure complex powder. The reasons leading to the above results were also discussed. (Edited author abstract) 7 Refs.
In-situ synthesis of terbium complex with salicylic acid (Sal) in silica matrix was made by a two-step sol-gel process. The terbium complex with salicylic acid was formed in sol-gel derived silica gel, and confirmed by the luminescence excitation spectra and infrared (IR) spectra. As compared with the pure terbium complex powder, the silica gel containing terbium complex exhibits its characteristic emission and presents a longer fluorescence lifetime than that for the pure complex. The luminescence properties of the complex containing silica gel were investigated and compared with those of both terbium doped the silica gel and the pure complex powder. The reasons leading to the above results were also discussed. (Edited author abstract) 7 Refs.