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Spline wavelet in the resolution of overlapping voltammetric peaks 被引量:2

Spline wavelet in the resolution of overlapping voltammetric peaks
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摘要 Spline wavelet transform is used to resolve overlapping voltammetric peaks. A suitable resolving factor is chosen to multiply the filters of spline wavelet and make it a peak resoluter. Simulated overlapping voltammetric peaks are processed by the peak resoluter and satisfactory results are obtained. Base-line separation can be achieved, the relative errors of peak position are less than 3.0%, and the relative errors of peak area are less than 5.0%. The effect of different resolving factors and spline wavelet basis are discussed. To test the procedure, two systems, cadmium (Ⅱ)-indium (Ⅲ) and lead (Ⅱ)-thallium (Ⅰ), are used. Spline wavelet transform is used to resolve overlapping voltammetric peaks. A suitable resolving factor is chosen to multiply the filters of spline wavelet and make it a peak resoluter. Simulated overlapping voltammetric peaks are processed by the peak resoluter and satisfactory results are obtained. Base-line separation can be achieved, the relative errors of peak position are less than 3.0%, and the relative errors of peak area are less than 5.0%. The effect of different resolving factors and spline wavelet basis are discussed. To test the procedure, two systems, cadmium (II)-indium (III) and lead (II)-thallium (I), are used.
出处 《Science China Chemistry》 SCIE EI CAS 1999年第2期145-152,共8页 中国科学(化学英文版)
关键词 SPLINE WAVELET RESOLUTION OVERLAPPING peaks. spline wavelet resolution overlapping peaks
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参考文献15

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共引文献15

同被引文献20

  • 1Zheng Jianbin,Zhang Hongquan,Gao Hong.Wavelet-Fourier self-deconvolution[J].Science in China Series B: Chemistry.2000(1)
  • 2Xiaoping Zheng,Jinyuan Mo,Peixiang Cai.Spline wavelet in the resolution of overlapping voltammetric peaks[J].Science in China Series B: Chemistry.1999(2)
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  • 8Xiaoping Zheng,Jinyuan Mo,Peixiang Cai.Spline wavelet in the resolution of overlapping voltammetric peaks[J].Science in China Series B: Chemistry.1999(2)
  • 9Zheng,J. B.,Zhao,R.,Zhang,H. Q.,Zhang,X. Q.,Zhao,X. Z.Wavelet transform and its application in processing of chemical signal[].Chinese Journal of Analytical Chemistry.1999
  • 10Zhang Yongqing,Mo Jinyuan,Xie Tianyao,Cai Peixiang.Spline wavelet self-convolution in processing overlapped peaks in capillary electrophoresis[].The Analyst.2000

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