无规离聚体/非极性溶剂体系的溶液行为

THE SOLUTION BEHAVIOR OF RANDOM IONOMER/ NONPOLARSOLVENT SYSTEMS

介绍了无规离聚体／非极性溶剂体系的溶液行为，以及溶液的浓度、离子含量、离聚体的母体聚合物的分子量、平衡离子的性质、中和度、小分子盐和溶剂极性对这一行为的影响，并阐明该体系的溶液行为在本质上是由于离子对的偶极吸引作用而产生的分子内和分子间的离子聚集行为。

he solution behavior of random ionomer/nonpolarsolvent systems and the effects of polymer concentration, ion content, the molecular weight of ionomer precursor, character of counterions, degree of neutralization, the presence of simple salts and the polarity of solvent on the solution behavior were introduced with 15 refrences. And it is expounded that the solution behavior of random ionomer/nonpolarsolvent systems in essentially the intraand intermolecular aggregation behavior due to dipolar attraction of ion pairs.