C_(60)-芳胺衍生物的制备及光谱特性研究

Preparation of C60aromatic Amine Derivative and Study of Its Spectrum Properties

以Ｃ６０、苯胺、乙二胺为原料，选择适当的反应途径，制备了Ｃ６０－芳胺衍生物，产物经红外吸收光谱、Ｈ质子核磁共振谱测定，推测了大致结构和反应机理．对其光致发光光谱的特性进行研究，并与Ｃ６０发光光谱比较，室温下观测到峰值位于４５０ｎｍ附近较强的光致发光现象．

In this paper, C60aromatic amine derivative is prepared by C60, aniline and ethylenediamine through several reaction steps. According to the determination of IR spectrum and HNMR spectrum, the structure of the product and the reaction mechanism have been inferred. Meanwhile, comparison of the PL spectrum between the derivative and C60, the derivative has increased PL phenomena at 450 nm at the room temperature.