十二烷氧基及十二酰氧基卟啉类化合物的合成

Synthesis of Dodecyloxy and Dodecanoyloxy Porphyrin Compounds

本文报道了．由５—对羟基苯基—１０，１５，２０－三对甲氧苯基卟啉（Ｉ）与１—溴代十二烷和月桂酰氯反应得到５－（Ｐ－十二烷氧苯基）－１０．１５，２０－三对甲氧苯基卟啉（Ｉ）和５－（Ｐ—十二酰氧苯基）－１０，１５，２０－三对甲氧苯基卟啉（Ⅲ），（Ⅱ）和（Ⅲ）是目前尚未见报道的新化合物，它们的结构经元素分析、红外光谱、核磁共振光谱及紫外可见光谱得以证实。

, The reactions of Dodecyl bromide and lauroyl chloide With 5 - (P - hydroxy phenyl) - 10. 15,20-tri- (P-methoxy phenyl)porphrin( I )gave 5- (P-Dodecyloxy phenyl)-10.15,20-tri-(P-methoxy phenyl)porphyrin( I )and 5-(P-Dodecaoyloxy phenyl)-10.15.20-tri-(P-methoxy phenyl)porphyrin( Ⅲ )The structure of the new synthesized compound ( I )and ( Ⅲ )was confirmed by elemental analysis,ultraviolet and Vis- sible . infrared Spectra and proton nuclear magnetic resonance spectra.