摘要
Some novel polyimides containing bisthiazole rings were prepared by reacting 2,2'-diamino-4, 4'-bisthiazole (DART) with different aromatic dianhydride. The polyimides obtained had inherent viscosities of 0.37-0.82 dl/g. Thermogravimetric analysis of the polyimides showed good thermal stability, the temperature at 5% weight loss being from 450 degrees to 560 degrees C. The permeability of two polymer membranes to H-2, O-2 and N-2 was determined, respectively. Three kinds of polyimide films were converted into electrical conductor by pyrolysis at high temperature in nitrogen atmosphere. The maximum room temperature conductivity as high as 3.9x10(2) S/cm for PI him pyrolyzed at 1200 degrees C for 10 min was obtained, and it was very stable in air.
Some novel polyimides containing bisthiazole rings were prepared by reacting 2,2'-diamino-4, 4'-bisthiazole (DART) with different aromatic dianhydride. The polyimides obtained had inherent viscosities of 0.37-0.82 dl/g. Thermogravimetric analysis of the polyimides showed good thermal stability, the temperature at 5% weight loss being from 450 degrees to 560 degrees C. The permeability of two polymer membranes to H-2, O-2 and N-2 was determined, respectively. Three kinds of polyimide films were converted into electrical conductor by pyrolysis at high temperature in nitrogen atmosphere. The maximum room temperature conductivity as high as 3.9x10(2) S/cm for PI him pyrolyzed at 1200 degrees C for 10 min was obtained, and it was very stable in air.
基金
This project was supported by the National Natural Science Foundation of China
