摘要
利用SOL-GEL技术成功地制备了ZrO_2-CaO膜管,这种膜管由于能控制氧的扩散速度,并能活化它,因而容易和甲烷反应,表现了高的选择性生成甲醇、甲醛。实验发现最佳的制膜条件为:焙烧温度是700~900℃,膜厚45~60gZr/cm ̄2,CaO的最佳值为X=0.08~0.15。实验也考察了最佳的反应条件,常压下反应温度为350℃,GHSV=8000~10000h ̄(-1)。在这样的条件下获得了95%的甲醇、甲醛选择性,大约1%转化率。
A new membrane tube-ZrO_2-CaO (CSZ) have been prepared by SOL--GELtechnology. It can control the diffusion velocity of oxgen.Oxgen diffusing through themembrane is activated and form active oxygen species which can easily react withmethane. So showing high selectivity to methanol and formaldehyde. the optimumpreparation condition is: Calcination temperature T = 700 -- 900 t, film thicknessb = 45 -- 60mgZr/cm', CaO additive amount x = 0.08 -- 0.15. The reaction condition have alsobeen investigated. At atmopheric pressure, the proper range of temperature is 350 oC orso, GHSV = 8000 -- 1000h--'. Under optimum reaction condiction we have got 95 %selectivity of methnaol and formaldehyde, about I % conversion of methane
出处
《五邑大学学报(自然科学版)》
CAS
1996年第1期21-26,共6页
Journal of Wuyi University(Natural Science Edition)