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Studies on the Magnetic Properties of Rare Earth Ions and Binuclear Complexes by ^(1)H NMR Single Spectrometer

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摘要 The magnetic susceptibility of rare earth ions and its binuclear complexes of 2-carbonylpropionic acid (pyridine-4-formyl) hydrazone (H2PPFH) was determined for the first time by 1H NMR Single Spectrometer in this paper. The magnetic exchange interaction was also studied. The results show that the 1H NMR method is convenient, reliable and the amount of sample required in the method is about one hundred of times less than that of Goury's method. The magnetic susceptibility of rare earth ions and its binuclear complexes of 2-carbonylpropionic acid (pyridine-4-formyl) hydrazone (H2PPFH) was determined for the first time by 1H NMR Single Spectrometer in this paper. The magnetic exchange interaction was also studied. The results show that the 1H NMR method is convenient, reliable and the amount of sample required in the method is about one hundred of times less than that of Goury's method.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 1995年第2期89-93,共5页 稀土学报(英文版)
基金 This progect was supported by the middlc-aged and youth natural scientifie foundation of Gansu province
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