摘要
MoS4Cu2Ag(Ph3P)3Br.H2O, fw = 1344, triclinic, space group P1 : a= 13.246(4),b = 20.314(6), c = 11 .995(4)A, α= 93.25(3)° β= 115.99(2)° γ = 74.44(3)° V= 2788.(2)A 3.Z= 2, Dc = 1 .60g cm-3, F(000)= 1340, μc=22.87cm-1, R = 0.060, Rw = 0.067. This is the first example or tetranuclear M-Mo-S cluster containing Cu and Ag together and the structure is a completed cubane that the Br atom bonds to Cu and Ag.
MoS4Cu2Ag(Ph3P)3Br.H2O, fw = 1344, triclinic, space group P1 : a= 13.246(4),b = 20.314(6), c = 11 .995(4)A, α= 93.25(3)° β= 115.99(2)° γ = 74.44(3)° V= 2788.(2)A 3.Z= 2, Dc = 1 .60g cm-3, F(000)= 1340, μc=22.87cm-1, R = 0.060, Rw = 0.067. This is the first example or tetranuclear M-Mo-S cluster containing Cu and Ag together and the structure is a completed cubane that the Br atom bonds to Cu and Ag.
