摘要
Ru111(NH3)6 in the cages of NaX zeolite was converted in the presence of CO+H2 into [Ru6(CO)18]2-, which was characterized by in-situ FTIR, UV-VIS and EXAFS spectroscopies. The material derived from [Ru6(CO)18]2-/NaX exhibited high calalytic activity in n-butane hydrogenolysis.
Ru111(NH3)6 in the cages of NaX zeolite was converted in the presence of CO+H2 into [Ru6(CO)18]2-, which was characterized by in-situ FTIR, UV-VIS and EXAFS spectroscopies. The material derived from [Ru6(CO)18]2-/NaX exhibited high calalytic activity in n-butane hydrogenolysis.
