摘要
The synthesis and properties of the title complex CH3OCOCH2CH2SnCl3. 2-HOC6H4CH+= NC6H4-3-CH3 are described. It crystallizes from benzene' in the monoclinic space group P2/n with Unit cell dimensions a= 10. 326 (3) .b=6. 815(8). c=12. 931 (6) A,β=111. 52(3)°, V=2088. 7(1),A3, Z=4, F(000)= 1040, μ= 16. 31cm-1. Dc =1. 67g/cm3 final R factor is 0. 037 for 3177 observed reflections, I≥3σ(I。). The tin atom in the structure of tile complex exists in a dis tored octahedral geomelry defined by three CI atoms, the C and O atoms of a chelating methoxycarbonylethyl group as well as an O atom derived from the Schiff base ligand.
The synthesis and properties of the title complex CH3OCOCH2CH2SnCl3. 2-HOC6H4CH+= NC6H4-3-CH3 are described. It crystallizes from benzene' in the monoclinic space group P2/n with Unit cell dimensions a= 10. 326 (3) .b=6. 815(8). c=12. 931 (6) A,β=111. 52(3)°, V=2088. 7(1),A3, Z=4, F(000)= 1040, μ= 16. 31cm-1. Dc =1. 67g/cm3 final R factor is 0. 037 for 3177 observed reflections, I≥3σ(I。). The tin atom in the structure of tile complex exists in a dis tored octahedral geomelry defined by three CI atoms, the C and O atoms of a chelating methoxycarbonylethyl group as well as an O atom derived from the Schiff base ligand.
基金
project supported by the National Natural Scicnces Foundation of China
