摘要
ZrO2 -supported Ru- Fe bimetallic clusters derived from Ru2 Fe(CO)12 or RuFe2(CO)1 2 displayed much higher activities in the hydrogenation of CO than that of mixed metal clusters or their monometallic clusters derived from Ru3(CO)1 2 and Fe2(CO)9 and that of conventional catalysts prepared from RuCl3 and Fe(NO3)3.One of the major object to research the Fischer--Tropsch synthesis over bimetalliccatalysts is the development of new catalyst systems which maximize the more desirablechemical products. In this paper, the effect of precursors for ZrOZ --supported Ru--Febimetallic and their monometallic clusters on the FT synthesis activities was investigated.
ZrO2 -supported Ru- Fe bimetallic clusters derived from Ru2 Fe(CO)12 or RuFe2(CO)1 2 displayed much higher activities in the hydrogenation of CO than that of mixed metal clusters or their monometallic clusters derived from Ru3(CO)1 2 and Fe2(CO)9 and that of conventional catalysts prepared from RuCl3 and Fe(NO3)3.One of the major object to research the Fischer--Tropsch synthesis over bimetalliccatalysts is the development of new catalyst systems which maximize the more desirablechemical products. In this paper, the effect of precursors for ZrOZ --supported Ru--Febimetallic and their monometallic clusters on the FT synthesis activities was investigated.
