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PREPARATION AND CATALYTIC ACTIVITY OF AMORPHOUS Ni-Pd-Si ALLOY POWDER BY BALL MILLING

PREPARATION AND CATALYTIC ACTIVITY OF AMORPHOUS Ni-Pd-Si ALLOY POWDER BY BALL MILLING
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摘要 Amorphous Ni-Pd-Si ribbons were partially crystallized by relaxation treatment then secondary amorphous Ni-Pd-Si alloy powder prepared by mechanical milling. The surface states of amorphous and crystalline Ni-Pd-Si powders were studied by XRD, TEM, AES and ESCA spectra. The catalytic activities of amorphous and crystalline powders in hydrogenation of styrene was measured.The result shows that the catalytic activity of amorphous Ni-Pd-Si powder was higher than that of crystalline one by 6 times in hydrogenation of styrene. Amorphous Ni-Pd-Si ribbons were partially crystallized by relaxation treatment then secondary amorphous Ni-Pd-Si alloy powder prepared by mechanical milling. The surface states of amorphous and crystalline Ni-Pd-Si powders were studied by XRD, TEM, AES and ESCA spectra. The catalytic activities of amorphous and crystalline powders in hydrogenation of styrene was measured.The result shows that the catalytic activity of amorphous Ni-Pd-Si powder was higher than that of crystalline one by 6 times in hydrogenation of styrene.
出处 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1994年第2期129-132,共4页 金属学报(英文版)
关键词 Ni-Pd-Si alloy ball milling hydragenation Ni-Pd-Si alloy, ball milling, hydragenation
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