摘要
An investigation on adsorption of NO on reduced Co-Mo/Al_2O_3 and Ru-Co-Mo/Al_2O_3 catalysts has been performed using FT-IR and MS spectroscopies. IR spectra of NO adsorption showed two bands at 1895 and 1800 cm_(-1), and NO--TPD profiles gave rise to several peaks at 353, 423 and 473 K, which are assigned to various Co-sites on the surface. Compared with Co-Mo/Al_2O_3, the adsorption rate, binding energy, and amount of NO adsorbed on Ru-Co-Mo/Al_2O_3 are very high.
An investigation on adsorption of NO on reduced Co-Mo/Al_2O_3 and Ru-Co-Mo/Al_2O_3 catalysts has been performed using FT-IR and MS spectroscopies. IR spectra of NO adsorption showed two bands at 1895 and 1800 cm_(-1), and NO--TPD profiles gave rise to several peaks at 353, 423 and 473 K, which are assigned to various Co-sites on the surface. Compared with Co-Mo/Al_2O_3, the adsorption rate, binding energy, and amount of NO adsorbed on Ru-Co-Mo/Al_2O_3 are very high.
基金
Natural Science Foundation of Chinese Academy of Sciences.
