SYNTHESIS AND CARACTERIZATION OF TERNARY COMPLEXES CONTAINING Cu(II),L-HISTIDINE AND NUCLEOTIDE

SYNTHESIS AND CARACTERIZATION OF TERNARY COMPLEXES CONTAINING Cu(II),L-HISTIDINE AND NUCLEOTIDE

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摘要 The ternary complexes containing Cu(II),L-His and nucleotide (5'-GMP and 5'-IMP)were synthesized and characterized.IR and ~1H NMR spectra show that Cu(II)binds to carboxylate oxygen and imidazole nitrogen of L-His and purine N_7 of 5'-GMP and 5'-IMP.The interaction of Cu(II)with Po_3^(2-)of 5'-GMP is present,but that for 5'-IMP is not present. The ternary complexes containing Cu(II),L-His and nucleotide (5'-GMP and 5'-IMP)were synthesized and characterized.IR and ~1H NMR spectra show that Cu(II)binds to carboxylate oxygen and imidazole nitrogen of L-His and purine N_7 of 5'-GMP and 5'-IMP.The interaction of Cu(II)with Po_3^(2-)of 5'-GMP is present,but that for 5'-IMP is not present.

作者 Chang Ping SHAO Fan ZHANG He Fu GUO Dallan Institute of Chemical Physics Chinese Academy of Sciences,Dalian,116023

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第9期735-736,共2页 中国化学快报（英文版）

关键词 SYNTHESIS AND CARACTERIZATION OF TERNARY COMPLEXES CONTAINING Cu 工工 L-HISTIDINE AND NUCLEOTIDE II GMP

分类号 O6 [理学—化学]

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Chinese Chemical Letters

1992年第9期

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SYNTHESIS AND CARACTERIZATION OF TERNARY COMPLEXES CONTAINING Cu(II),L-HISTIDINE AND NUCLEOTIDE

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