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TEMPERATURE—DEPENDENCE OF CARRIER ION NUMBER IN SOLID POLYETHER MEDIA

TEMPERATURE—DEPENDENCE OF CARRIER ION NUMBER IN SOLID POLYETHER MEDIA
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摘要 The temperature—dependence of cationic conductivity,mobility and carrier generation in the blend of macromolecular lithium salt and copoly- ether were investigated.The population of free—ions was found to decrease exponentially with rising temperature.However,this“anomalous”behavior of salt—dissociation has little effect on the temperature—dependence of con- ductivity,since it is ion mobility rather than carrier ion number which predominates ion transport process. The temperature—dependence of cationic conductivity,mobility and carrier generation in the blend of macromolecular lithium salt and copoly- ether were investigated.The population of free—ions was found to decrease exponentially with rising temperature.However,this“anomalous”behavior of salt—dissociation has little effect on the temperature—dependence of con- ductivity,since it is ion mobility rather than carrier ion number which predominates ion transport process.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第9期765-766,共2页 中国化学快报(英文版)
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