STUDY ON 1,2,3-DIAZAPHOSFHOLE V THE REACTION OF 1,2,3-DIAZAPHOSPHOLE WITH 2-BUTYNE-1,4-DIOL

STUDY ON 1,2,3-DIAZAPHOSFHOLE V THE REACTION OF 1,2,3-DIAZAPHOSPHOLE WITH 2-BUTYNE-1,4-DIOL

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摘要 2-Acetyl-5-methyl-2H-1,2,3—diaraphosphole 1 reacted with 2—butyne—1, 4—diol to form a tricoordinated phosphorus compound 7, which then rearranged to a novel 2, 3-disubstituted-1, 3-diene.Similar rearrangement has been observed when diphenylchloropbosphine reacted with 2-butyne—1,4-diol 2-Acetyl-5-methyl-2H-1,2,3—diaraphosphole 1 reacted with 2—butyne—1, 4—diol to form a tricoordinated phosphorus compound 7, which then rearranged to a novel 2, 3-disubstituted-1, 3-diene.Similar rearrangement has been observed when diphenylchloropbosphine reacted with 2-butyne—1,4-diol

作者 Ru Yu CHEN, Bao Zhong CAI and Ke Sheng FENG Institute of Elemento-Organic Chemistry, Nankai University, Tianj in 300071

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第3期157-158,共2页 中国化学快报（英文版）

关键词 ppm Ph Li STUDY ON 1 2 3-DIAZAPHOSFHOLE V THE REACTION OF 1 2 3-DIAZAPHOSPHOLE WITH 2-BUTYNE-1 4-DIOL Chen TMS

分类号 O6 [理学—化学]

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Chinese Chemical Letters

1992年第3期

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STUDY ON 1,2,3-DIAZAPHOSFHOLE V THE REACTION OF 1,2,3-DIAZAPHOSPHOLE WITH 2-BUTYNE-1,4-DIOL

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