SYNTHESIS AND REACTIVITY OF OXOPEROXOMOLYBDENUM(Ⅵ)COMPLEXES:THE ACTIVE SPECIES IN THE HALCON EPOXIDATION PROCESS

SYNTHESIS AND REACTIVITY OF OXOPEROXOMOLYBDENUM(Ⅵ)COMPLEXES:THE ACTIVE SPECIES IN THE HALCON EPOXIDATION PROCESS

下载PDF

导出

摘要 Two oxoperoxomolytxlenum(Ⅵ)complexes,MoO(O_2)(OCH_2CH_2)_2NH.H_2O(5)and MoO(O_2)(OCH(CH_3)CH_2)_2 NH(6)have been synthesized by the reaction of MoO_2(OCH_2CH_2)_2NH·CH_3OH(3)and MoO_2(OCH(CH_3)CH_2)_2NH(4)with tert-butyl hy- droperoxide,and are active to epoxidize cyclohexene. Two oxoperoxomolytxlenum(Ⅵ)complexes,MoO(O_2)(OCH_2CH_2)_2NH.H_2O(5)and MoO(O_2)(OCH(CH_3)CH_2)_2 NH(6)have been synthesized by the reaction of MoO_2(OCH_2CH_2)_2NH·CH_3OH(3)and MoO_2(OCH(CH_3)CH_2)_2NH(4)with tert-butyl hy- droperoxide,and are active to epoxidize cyclohexene.

作者 Zheng Rong LU Department of Chemistry,Wuhan University,Wuhan 430072 Yuan Qi YIN Dao Sen JIN Lanzhou Institute of Chemical Physics,Academia Sinica,Lanzhou 730000

出处《Chinese Chemical Letters》 SCIE CAS CSCD 1992年第12期1003-1006,共4页 中国化学快报（英文版）

关键词 HALCON VI COMPLEXES SYNTHESIS AND REACTIVITY OF OXOPEROXOMOLYBDENUM

分类号 O6 [理学—化学]

引文网络
相关文献

1Yun Qi TIAN(Department of Chemistry. Liaoning Uuiversity, Shenyang 110036)Jian TONG(Analysis & Test Center of Liaoning Uuiversity, Shenyang 110036).Proton-Template Synthesis of a П─Conjugated Macrocycle and Structure of its Ni_2(Ⅱ)—Complex[J].Chinese Chemical Letters,1997,8(2):107-110.
2Zhong E LU Yi Liang MA Song Shan GUO Ke Qian CHEN Department of Chemistry,Suzhou University,Suzhou 215006 Zheng Min SUN Laboratory of Solid Microstructures,Nanjing University,Nanjing 210008.SYNTHESIS OF 2-(4'-ALKOXYPHENYL)-6-SUBSTITUTED BENZOTHIAZOLES AND THEIR LIQUID CRYSTAL CHARACTERS[J].Chinese Chemical Letters,1991,2(9):727-728.
3陶祖贻,杨更亮.THERMODYNAMICS OF BINARY AND TERNARY ION EXCHANGE SYSTEMS[J].Chinese Science Bulletin,1987,32(18):1240-1244.
4王长松,李安东,刘大晨,刘罡.聚(N-十二烷基-3-丙酰基吡咯)的合成研究[J].沈阳化工学院学报,2004,18(4):255-258.
5Yong Qiang TU Department of Chemistry, Lanzhou University, Lanzhou, 730000.A NEW SESQUITERPENE FROM CELASTRUS ROSTHONIANUS[J].Chinese Chemical Letters,1991,2(12):935-936. 被引量：1
6Wei Zhong ZHENG,Xian Yuan WANG,Guang Nian LI.THE HYDROXYLATON OF INACTIVE HYDROCARBONS WITH ACTIVE CARBON SUPPORTED METALLOPORPHYRINS[J].Chinese Chemical Letters,1993,4(1):45-46.
7Lin HUANG,Wen Gui GUO,An Ming LII,Da Ming LI,Yi De XUState Key Laboratory of Catalysis,Dalian Institute of Chemical Physics,P.O.Box 110,Dalian 116023.DISPERSION EFFECTS OF CLUSTER-DERIVED Rh ON SiO_2 OH ETHYLENE HYDROFORMYLATION[J].Chinese Chemical Letters,1992,3(5):401-402.
8Yun TANG,Kai Xian CHEN,Hua Liang JIANG,Guo Zhang JIN,Ru Yun JI(Shanghai Institute of Materia Medica. Chinese Academy of Sciences,294 Taiyuan Road, Shanghai 200031).STUDIES　ON　DOPAMINE　RECEPTORS　AND　TETRAHYDROPROTOBERBERINES．Ⅲ．3D－QSAR　STUDY　ON　TETRAHYDROPROTOBERBERINES　USING　COMFA　APPROACH[J].Chinese Chemical Letters,1996,7(3):249-252.
9TG.Nieh(Lawrence Livermore National Laboratory, P.O.Box 808, L-350, Livermore, CA 94551, USA ).Structure and Deformation of Intermetallic Beryllides[J].Journal of Materials Science & Technology,1994,10(6):391-405.
10Chong Zheng FAN Chang Sui WANG Sheng Jun WANG (The University of Science and Technology of China,Hefei,Anhui,P.R.China) You Shi WU (Institute of Machine & Electricity of An Hui Province,Wu Hu) D.L.TRIMM M.S.WAINWRIGHT (The University of New South Wales,Australia).SINERING BEHAVIOUR OF RANEY-COPPER CATALYST IN VARIOUS ATMOSPHERES[J].Chinese Chemical Letters,1990,1(3):279-282.

Chinese Chemical Letters

1992年第12期

浏览历史

内容加载中请稍等...

SYNTHESIS AND REACTIVITY OF OXOPEROXOMOLYBDENUM(Ⅵ)COMPLEXES:THE ACTIVE SPECIES IN THE HALCON EPOXIDATION PROCESS

相关作者

相关机构

相关主题

浏览历史