摘要
Recent development of the dynamic analysis technique has made it possible to measure separately kinetic parameters of a catalytic reaction as well as to study the effect of catalyst preparation parameters. But its application is still limned to first-order reaction. This work is aimed to demonstrate in some detail that,by comparison of the reaction rate expressions with the two-step mechanism used in catalytic kinetics and dynamic analysis, these methods can be extended to non-first-order reaction, and the kinetic parameters measured by dynamic techniques are interpreted for different reaction mechanisms.
Recent development of the dynamic analysis technique has made it possible to measure separately kinetic parameters of a catalytic reaction as well as to study the effect of catalyst preparation parameters. But its application is still limned to first-order reaction. This work is aimed to demonstrate in some detail that,by comparison of the reaction rate expressions with the two-step mechanism used in catalytic kinetics and dynamic analysis, these methods can be extended to non-first-order reaction, and the kinetic parameters measured by dynamic techniques are interpreted for different reaction mechanisms.
