羟羧桥连四核钴配合物的合成和催化活性研究

STUDIES ON THE SYNTHESIS,PROPERTLES AND CATALYTICAL ACTIVITIES OF THE COMPLEX[Co_2(Ⅲ)Co_2(Ⅱ)(CH_3CH_2CH_2COO)_6(OH)_4(H_2O)_4]

作者利用丁酸钴、正丁酸和环巳酮均相体系,合成了羟羧桥连丁酸钴四核配合物.通过红外、核磁、差热热重等分析测试手段对产品进行了组成和结构的初步确定。以环巳烷为底物进行了催化性能的初步研究。

The title complex has been prepared in the system of cobalt butyrate,butanoic acid and cyclohexaone It has been characterized by elemental analysis IR,H^1NMR, TG-DTA The data show that the complex has two kinds of bridginggroups:two butyrates and four hydroxyls The oxidation of hexane by ox(?)gen on the complex has also been studied