α-溴汞化羰基化合物与N-亚硝基乙酰芳胺的反应

THE REACTION OF α-BROMOMERCURI-SUBSTITUTED CARBONYL COMPOUNDS WITH N-NITROSOACETANILIDES

用作芳基自由基来源的N-亚硝基乙酰芳胺与α-溴汞化羰基化合物一起加热时,生成溴化芳基汞,副产物及ESR研究说明反应为自由基过程.

Arylmercuric bromides were obtained in good yields by heating α-bromomercuri-substituted carbonyl compounds with the aryl radical prccusor, N-nitrosoacetanilides. Studies of the structure of the by-products and ESR indicate that the reaction is a free radical process.