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A Theoretical Studies on the Thermolysis Mechanism of α-Aminonitrile

A Theoretical Studies on the Thermolysis Mechanism of α-Aminonitrile
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摘要 Introduction α-Aminonitrile(or aminoacetonitrile) is a kind of reactive bioorganic molecules, and it may exist in insterstellar clouds. its importance lies in that a-aminonitrile may play a role in the generation of large carbon-nitrogen chain molecules. By means of flash vacuum thermolysis and gas-solid reaction (FVT-GSR) tech-nique, Guillemin, et al., studied the thermolysis of a-aminonitrile, they considered that the elimination of HCN (shown as following) is a key step in many reactions of α-
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1992年第4期480-482,共3页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China Jiangxi Province.
关键词 THERMOLYSIS α-Aminonitrile Transition state IRC path Thermolysis, α-Aminonitrile, Transition state, IRC path
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