摘要
A new type of complex solid superacid catalyst WO_3-ZrO_2-SO_4^(2-)with an acid strength H_0≤-16.04 was prepared by kneading Zr(OH)_4 or amorphous ZrO_2 with tungstic acid(H_2WO_4)(W/Zr=0.15),followed by exposing this complex hydroxides to 0.5 tool/L H_2SO_4,calcining in air at 700～800℃ for 3h.This catalyst possesses both strong Bronsted acidity and strong Lewis acidity experimentally showed by IR observation of pyridine absorbed on it.XPS and AES techniques were employed to examine the valence states of tungsten, zirconium,sulfur and their interactions.The structure of sulfur species was studied by infrared spectroscopy and a structure model of active site was proposed upon these results.
A new type of complex solid superacid catalyst WO_3-ZrO_2-SO_4^(2-)with an acid strength H_0≤-16.04 was prepared by kneading Zr(OH)_4 or amorphous ZrO_2 with tungstic acid(H_2WO_4)(W/Zr=0.15),followed by exposing this complex hydroxides to 0.5 tool/L H_2SO_4,calcining in air at 700～800℃ for 3h.This catalyst possesses both strong Bronsted acidity and strong Lewis acidity experimentally showed by IR observation of pyridine absorbed on it.XPS and AES techniques were employed to examine the valence states of tungsten, zirconium,sulfur and their interactions.The structure of sulfur species was studied by infrared spectroscopy and a structure model of active site was proposed upon these results.
基金
The project was financed by National Natural Science Foundation of China.
