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AN ELECTRON MICROSCOPE STUDY OF MINERAL GROUP OF FRANCKEITE

AN ELECTRON MICROSCOPE STUDY OF MINERAL GROUP OF FRANCKEITE
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摘要 Franckeite and cylindrite of franckite mineral group were examined in the transmission electron microscope. Selected-area electron diffraction indicated that in the structure exists a long period, belonging to an incommensurate modulation period. The incommensurate modulation in this kind of minerals results from sine undular structure sheets. The excellent correspondence between high resolution simulated computer image and observed image was obtained on the basis of the structure of franckeite and cylindrite which was put forward in this paper. First, the fact that in the structures of franckeite and cylindrite exist two kinds of structure sheets whose lattices are different has been proved by experiment, i. e. false tetragonal symmetrical galena structure sheets(t sheets)and false hexagonal SnS_2 sheets(h sheets). The two kinds of sheets are packed in order of htht… Franckeite and cylindrite of franckite mineral group were examined in the transmission electron microscope. Selected-area electron diffraction indicated that in the structure exists a long period, belonging to an incommensurate modulation period. The incommensurate modulation in this kind of minerals results from sine undular structure sheets. The excellent correspondence between high resolution simulated computer image and observed image was obtained on the basis of the structure of franckeite and cylindrite which was put forward in this paper. First, the fact that in the structures of franckeite and cylindrite exist two kinds of structure sheets whose lattices are different has been proved by experiment, i. e. false tetragonal symmetrical galena structure sheets(t sheets)and false hexagonal SnS<sub>2</sub> sheets(h sheets). The two kinds of sheets are packed in order of htht…
出处 《Science China Chemistry》 SCIE EI CAS 1992年第6期745-757,共13页 中国科学(化学英文版)
基金 Project supported by the National Natural Science Foundation of China.
关键词 franckeite cylindrite incommensurate-modulated structure selectedarea ELECTRON DIFFRACTION high RESOLUTION ELECTRON MICROSCOPE technique. franckeite, cylindrite, incommensurate-modulated structure, selectedarea electron diffraction, high resolution electron microscope technique.
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