摘要
In order to develop a new field of the enzyme design using steroid template and explore the hydrophobic action of enzyme model, we investigated, for the first time, the catalytic properties of steroid-metalloporphyrins towards oxidation of isopropylbenzene. It has been found out that the catalytic activities of metalloporphyrins have been greatly increased because of the presence of the hydrophobic plane of steroids. This fact reveals the
<正> In order to develop a new field of the enzyme design using steroid template and explore the hydrophobic action of enzyme model, we investigated, for the first time, the catalytic properties of steroid-metalloporphyrins towards oxidation of isopropylbenzene. It has been found out that the catalytic activities of metalloporphyrins have been greatly increased because of the presence of the hydrophobic plane of steroids. This fact reveals the importance
基金
Project supported by the National Natural Science Foundation of China
