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Synthesis and Properties of Dinuclear Cu( Ⅱ ) Complexes Derived from Oxamidobis(propionato)cuprate( Ⅱ )

Synthesis and Properties of Dinuclear Cu( Ⅱ ) Complexes Derived from Oxamidobis(propionato)cuprate( Ⅱ )
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摘要 Three dinuclear complexes were synthesized and designated as Cu(obp)CuL where obp =oxamidobis(propionato), L=2,2' -bipyridyl(bpy) (1), 1 , 10-phenathroline(phen)(2) and 5-nitro-1, 10-phenathroline(NO2-phen)(3). The complexes were characterized by elemental analyses, in fared and electronic spectra, magnetic susceptibilities and ESR spectra, indicating antiferromagnetic spin exchange interactions between metal ions. Three dinuclear complexes were synthesized and designated as Cu(obp)CuL where obp =oxamidobis(propionato), L=2,2' -bipyridyl(bpy) (1), 1 , 10-phenathroline(phen)(2) and 5-nitro-1, 10-phenathroline(NO2-phen)(3). The complexes were characterized by elemental analyses, in fared and electronic spectra, magnetic susceptibilities and ESR spectra, indicating antiferromagnetic spin exchange interactions between metal ions.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1991年第1期18-21,共4页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China
关键词 Oxamido bridge Dicopper complex Magnetic property Oxamido bridge, Dicopper complex, Magnetic property
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