摘要
<正> Two new binuclear copper（Ⅱ） complexes, [Cu（oxpn）CuL]（ClO4）2, have been synthesizedand characterized, where oxpn is N,N’ bis（3-aminopropyl）oxamido and L is 1,10-phenan-throline （phen） or 5-nitro-1,10-phenanthroline （NO2-phen）. The crystal structure and vari-able-temperature magnetic susceptibility （4- 300 K） of the Complex （L=phen） have beendetermined. Crystal data: orthorhombic system, space group Pnma, with a = 10.433（1）, b11.458（2）, c = 21.999（2）A, z = 4. Every copper（Ⅱ） ion is in a square pyramidal environment.The two copper（Ⅱ） ions are linked by μ-oxamido bridge and the separation of them is 5.208A. The singlet-triplet energy gap J was found equal to -452.92cm-1, indicating that astrongantiferromagnetic spin-exchange interaction operates between the copper（Ⅱ） ions.
Two new binuclear copper（Ⅱ） complexes, [Cu（oxpn）CuL]（ClO<sub>4</sub>）<sub>2</sub>, have been synthesizedand characterized, where oxpn is N,N’ bis（3-aminopropyl）oxamido and L is 1,10-phenan-throline （phen） or 5-nitro-1,10-phenanthroline （NO<sub>2</sub>-phen）. The crystal structure and vari-able-temperature magnetic susceptibility （4- 300 K） of the Complex （L=phen） have beendetermined. Crystal data: orthorhombic system, space group Pnma, with a = 10.433（1）, b11.458（2）, c = 21.999（2）A, z = 4. Every copper（Ⅱ） ion is in a square pyramidal environment.The two copper（Ⅱ） ions are linked by μ-oxamido bridge and the separation of them is 5.208A. The singlet-triplet energy gap J was found equal to -452.92cm<sup>-1</sup>, indicating that astrongantiferromagnetic spin-exchange interaction operates between the copper（Ⅱ） ions.
基金
Project supported by the National Natural Science Foundation of China.
