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TUNNELING CORRECTIONS TO TRANSITION STATE THEORY FOR REACTION H+ H_2(v=0)→H_2(all v)+H

TUNNELING CORRECTIONS TO TRANSITION STATE THEORY FOR REACTION H+ H_2(v=0)→H_2(all v)+H
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摘要 Ⅰ. INTRODUCTIONThe tunneling was not considered in conventional transition state theory (TST). Especially within low reaction temperature the calculation of the conventional TST can bring about obvious errors. In 1979, Kuppermann in his article about TST stressed the state-to-state TST. His theory used the transmission coefficient. On the basis of Kuppermann’s theory it is not difficult to consider the tunneling.
机构地区 Department of Physics
出处 《Chinese Science Bulletin》 SCIE EI CAS 1991年第3期193-196,共4页
关键词 transmission probability transition state PARTITION function. transmission probability, transition state, partition function.
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