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THE RELATION OF SEQUENCE DISTRIBUTIONS OF S-SBR TO ITS MOLECULAR WEIGHT DISTRIBUTIONS

THE RELATION OF SEQUENCE DISTRIBUTIONS OF S-SBR TO ITS MOLECULAR WEIGHT DISTRIBUTIONS
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摘要 The relationship between sequence distributions and molecular weight distributions of S-SBR, obtained from styrene and butadiene anionic copolymerization at various conversions with THF/Li^+ as an initiator has been studied by ^(13)C-NMR,GPC. The results showed that the molecular weight distributions of the copolymer couldbe correlated sophisticatedly to the binary sequcne distributions or the monomer unit distributions of the copolymer in a corrected Poisson's distribution from. The relationship between sequence distributions and molecular weight distributions of S-SBR, obtained from styrene and butadiene anionic copolymerization at various conversions with THF/Li^+ as an initiator has been studied by ^(13)C-NMR,GPC. The results showed that the molecular weight distributions of the copolymer couldbe correlated sophisticatedly to the binary sequcne distributions or the monomer unit distributions of the copolymer in a corrected Poisson's distribution from.
出处 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1991年第4期283-288,共6页 高分子科学(英文版)
关键词 Molecular weight distributions Sequence distributions BUTADIENE STYRENE Living copolymerization Molecular weight distributions Sequence distributions Butadiene Styrene Living copolymerization
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